Learning focus

Develop precise chemical language, connect equations and practical observations, interpret periodic trends and apply salt-preparation rules to unfamiliar examples.

Proton definition

An acid is a proton donor and a base is a proton acceptor. A proton in this context is H+. The definition focuses on transfer during a reaction. Hydrochloric acid donates H+ to water or to a base, while OH- accepts H+ to make H2O.

An acid transfers a proton and a base accepts it.
An acid transfers a proton and a base accepts it.
Identifying the acid and base

Follow the proton. The species that loses H+ is the acid; the species that gains H+ is the base. In HCl + H2O -> H3O+ + Cl-, HCl donates H+ and is the acid, while water accepts H+ and acts as the base. The hydronium ion notation may appear in wider chemistry, although the syllabus commonly writes H+(aq).

Hydroxide ions accept protons to form water.
Hydroxide ions accept protons to form water.
Relationship to neutralisation

Many neutralisation reactions can be understood as proton transfer. A metal oxide contains oxide ions that accept protons, and a metal hydroxide contains hydroxide ions that accept protons. The resulting water is formed when the acidic proton becomes bonded to oxygen-containing species.

Limits of simple labels

A substance can act as an acid in one reaction and as a base in another if the reaction partners differ, although most syllabus examples have clear roles. The useful method is to analyse actual proton transfer rather than memorise a permanent label without context.

Practical or data skill

Use molecular cards to show proton transfer between HCl and OH-. Mark the proton before and after the reaction and identify donor and acceptor.

Examination tip

State both parts of the definition: acid donates H+; base accepts H+.

Review questions and suggested answers
Question 1

What is a proton donor?

Suggested answer

An acid.

Question 2

What does a base accept?

Suggested answer

A proton, H+.

Question 3

In H+ + OH- -> H2O, which species acts as the base?

Suggested answer

OH-, because it accepts H+.