Learning focus

Develop precise chemical language, connect equations and practical observations, interpret periodic trends and apply salt-preparation rules to unfamiliar examples.

Ethanoic acid equation

Ethanoic acid dissociates partially: CH3COOH(aq) <=> H+(aq) + CH3COO-(aq). The ethanoate ion is the conjugate residue after the proton is donated. Most particles remain as CH3COOH at equilibrium.

The reversible arrow represents partial dissociation of ethanoic acid.
The reversible arrow represents partial dissociation of ethanoic acid.
Meaning of the reversible arrow

The equilibrium symbol shows that forward dissociation and reverse recombination occur. It does not imply equal concentrations. For a weak acid, the equilibrium position is mainly on the molecular side.

A weak acid can still be concentrated.
A weak acid can still be concentrated.
Particle interpretation

A particle diagram for a weak acid should contain many intact HA or CH3COOH molecules and relatively few H+ and anion particles. A strong acid at the same concentration should show almost only ions.

Reaction rate comparison

A weak acid may continue to dissociate as H+ ions are consumed during reaction. It can eventually react with the same stoichiometric quantity of a reactant as a strong monoprotic acid of the same concentration, while showing a slower initial rate because its initial H+ concentration is lower.

Practical or data skill

Use particle cards to represent partial dissociation and dynamic equilibrium. Remove H+ cards to model reaction and allow additional molecules to dissociate.

Examination tip

Partial dissociation does not mean that weak-acid molecules are physically diluted.

Review questions and suggested answers
Question 1

Write the ethanoic acid dissociation equation.

Suggested answer

CH3COOH(aq) <=> H+(aq) + CH3COO-(aq).

Question 2

Why is a reversible arrow used?

Suggested answer

Dissociation is partial and ions can recombine.

Question 3

Which particles are most numerous in a weak acid?

Suggested answer

Undissociated acid molecules.